Based on the research data of 216 cites in China from 2011 to 2018,this paper uses empirical methods such as spatial panel model and dynamic panel threshold model to empirically test the theoretical hypothesis of land resource land resource misallocation, industrial structure influence on haze pollution. The results show that the land resource misallocation behavior of local and neighboring governments directly aggravates the local haze pollution level; the land resource misallocation behavior of local governments indirectly aggravates the local haze pollution through industrial structure, while the impact of land resource misallocation behavior of neighboring governments on local haze pollution through industrial structure channels is not obvious; moreover, there is a significant threshold effect of industrial structure in the mismatch of haze pollution. Through the comparison of time difference，it is found that the reform of market allocation of land elements has a significant restraining effect on haze pollution.