Geopolitical conflicts have exacerbated volatility in global energy markets, highlighting the importance of national energy resilience within the overall national security perspective. This paper, anchored in an innovation-driven development strategy, develops a two-dimensional evaluation matrix of “esource endowment-industrial development”. Utilizing the entropy weight TOPSIS method, coupling coordination degree model, kernel density estimation, and the Catboost algorithm, the research examines the coordination between energy resilience and technological innovation, as well as their spatio-temporal evolution across 30 Chinese provinces (excluding Tibet, Hong Kong, Macao, and Taiwan) from 2011 to 2022. Additionally, the SHAP framework is employed to identify key influencing factors. The findings indicate that: (1) Both energy resilience and technological innovation have steadily increased, though their development is marked by imbalances and inadequacies.(2) The coordination between them has improved markedly over time, yet distinct regional spatial differentiation persists, forming a hierarchical pattern of “industry- leading regions, innovation- driven and comprehensive development lagging regions, and resource- dominated regions pursuing growth”.(3) Influencing factors vary by region, exhibiting different thresholds and facilitative mechanisms, with disparities in technological innovation levels being the primary drivers of coordination differences. Based on these results, the study recommends governance strategies to bridge the "technology gap" synchronize resource management to implement an "energy revolution" and promote coordinated development tailored to local contexts.